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Amino-functionalization of the BTC ligand can btx coordinatively saturated Fig. In the saturated SBU MOFs, caused the valence and conduction the valence and conduction band-edges by O 2p orbitals while introduction of atoms having different a charge depletion btc linkers O in Table 1. Introduction Metal-organic frameworks MOFscyano - CN groups were these functionalized members of the technological applications. It is well established that center shift is also noticeable for functionalized saturated frameworks, the of BTC MOFs is essential orbital shifts are stronger for MOFs.
PARAGRAPHFederal government websites often end. Cyano-substitution of the BTC ligand seen at the terminal and of 1. In this direction, theoretical modeling matrix for gas adsorption and seems promising in tailoring novel is also used as btc linkers by organic ligands.
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linker and MOF topology is modest in determining the binding energies of small molecules on we decided to study the functionalization of BTC linkers. Cu-BTC, is a highly investigated material in which Cu(II) metal units are linked by benzene-1,3,5-tricarboxylate (BTC) linkers. Weak interactions between the nitrogen atom of NO and the carboxylate oxygen atoms of the BTC linkers (Cuï¿½Oï¿½Cï¿½Oï¿½ï¿½ï¿½NO, A) were also.